Ethyl Maltol

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Ethyl Maltol (CAS 4940-11-8) is a synthetic perfumery ingredient known for its intensely sweet, caramellic, and jammy aroma reminiscent of candyfloss and fruit preserves. With a significantly higher potency than maltol—four to six times stronger—it is widely used to impart warmth and sweetness to gourmand, fruity, and vanilla-based compositions. Its strong diffusion and high odor tenacity make it a key modifier in both perfumery and flavor applications, especially in enhancing edible or nostalgic scent profiles.

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Premium Synthetic Ingredient for Perfumery

Ethyl Maltol (CAS 4940-11-8) is a synthetic perfumery ingredient known for its intensely sweet, caramellic, and jammy aroma reminiscent of candyfloss and fruit preserves. With a significantly higher potency than maltol—four to six times stronger—it is widely used to impart warmth and sweetness to gourmand, fruity, and vanilla-based compositions. Its strong diffusion and high odor tenacity make it a key modifier in both perfumery and flavor applications, especially in enhancing edible or nostalgic scent profiles.

Premium Synthetic Ingredient for Perfumery

Ethyl Maltol (CAS 4940-11-8) is a synthetic perfumery ingredient known for its intensely sweet, caramellic, and jammy aroma reminiscent of candyfloss and fruit preserves. With a significantly higher potency than maltol—four to six times stronger—it is widely used to impart warmth and sweetness to gourmand, fruity, and vanilla-based compositions. Its strong diffusion and high odor tenacity make it a key modifier in both perfumery and flavor applications, especially in enhancing edible or nostalgic scent profiles.

Synthetic Ingredient Overview

  • 🏭 Manufacturer: Commonly available (various producers)

  • 🔎 Chemical Name: 2-ethyl-3-hydroxy-4H-pyran-4-one

  • 🧪 Synonyms: EM, Ethylpyromeconic acid

  • 🧬 Chemical Formula: C₇H₈O₃

  • 📂 CAS N°: 4940-11-8

  • 📘 FEMA: 3487

  • ⚖️ MW: 140.14 g/mol

  • 📝 Odor Type: Sweet → Gourmand (Caramellic)

  • 📈 Odor Strength: High

  • 👃🏼 Odor Profile: Sweet, sugary, burnt cotton candy, caramelised, jammy strawberry-like

  • 👅 Flavor Profile: Burnt sugar, strawberry jam, vanilla, cotton candy, creamy

  • ⚗️ Uses: Sweetening and stabilizing gourmand or fruity accords, especially in vanilla, chocolate, caramel, and red berry themes.

  • 🧴 Appearance: White crystalline solid

What is Ethyl Maltol?

Ethyl Maltol is a synthetic heterocyclic compound and a homolog of maltol, structurally defined as a hydroxypyranone with an ethyl substitution. First isolated from larch tree bark, it is now industrially synthesized due to global demand in both the flavor and fragrance sectors. Its thermal stability, olfactory intensity, and compatibility with a wide array of aromatic materials make it a benchmark ingredient for sweet, edible, or nostalgic scent construction.

In perfumery, Ethyl Maltol acts as a sweetness modulator, often layered with vanillin, coumarin, and musks to provide depth, roundness, and lasting appeal. Used at high dilution, it reinforces candy-like notes and lends emotional familiarity to compositions. It is commonly found in gourmand, fruity-floral, oriental, and fantasy accords.

Olfactory Behavior & Perfumery Applications

Odor Perception:

  • Top Notes: Jammy fruit, sugary red berries

  • Heart/Base Notes: Caramelized cotton candy, vanilla fudge, burnt sugar

Functional Roles in Formulation:

  • Sweetener: Intensifies gourmand and fruity profiles

  • Blender: Adds roundness and projection to vanilla, chocolate, and fruit

  • Fixative: Reinforces base notes by enhancing longevity and body

Typical Applications:

  • Candy-style gourmand perfumes (e.g. cotton candy, toffee, caramel themes)

  • Fruity florals (strawberry-rose, peach-gardenia)

  • Oriental vanillas and modern "dessert" fragrances

  • Industrial masking agent for harsh or rubbery notes in consumer products

Industrial and Technical Uses

  • Flavor Industry: Found in chocolate, caramel, red berry, and soda-type flavors; commonly used at 50–1000 ppm, higher in confectionery or chewing gum

  • Pharmaceuticals & Tobacco: Enhancer for taste-masking and aromatic properties

  • Cosmetics & Personal Care: Masking agent and sweetener in balms and creams

  • Functional Products: Adds a palatable note to industrial formulations

Regulatory & Safety Overview

  • IFRA Status: Not currently restricted (IFRA 51st)

  • EU Allergen List: Not listed under Annex III allergens

  • FEMA GRAS: 3487 (recognized for flavor use)

  • REACH: Registered; no hazard classification under typical use

  • Toxicology Summary:

    • Low oral toxicity

    • No skin sensitization reported under standard conditions

    • Safe within typical fragrance concentrations

    • Avoid overheating or concentrated exposure in manufacturing

⚠️ Ethyl Maltol is powerful even at low dosage. Overuse can overwhelm a composition and distort top-note brightness.

Additional Notes on Production and Use

Ethyl Maltol is synthesized via pyranone chemistry, often from furfural or other carbohydrate-derived intermediates. A key method is catalytic hydrogenation followed by oxidation.

Its use in perfumery dates back to the late 20th century, when its strength and versatility surpassed maltol. It is also an essential component in modern electronic cigarette flavors and heat-stable bakery aromas.


Sources

  • Perfume and Flavor Chemicals, Steffen Arctander

  • The Chemistry of Fragrance, D. Pybus & C. Sell

  • FEMA GRAS Database

  • NCBI PubChem CID 5364409 – Ethyl Maltol

  • Gerard Mosciano, P&F Journal 1991

  • McGinty, Letizia & Api, IFRA Safety Assessments

  • Hamza, 2023 – Ethyl Maltol in Thermally Processed Foods

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